Cations in olivine,Part 1: Calcium partitioning and calcium-magnesium distribution between olivines and coexisting melts,with petrologic applications   总被引：2，自引：0，他引：2  

Amy J. G. Jurewicz  E. Bruce Watson 《Contributions to Mineralogy and Petrology》1988,99(2):176-185

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Fluids in the lithosphere, 2. Experimental constraints on CO₂ transport in dunite and quartzite at elevated P-T conditions with implications for mantle and crustal decarbonation processes     

James M. Brenan  E. Bruce Watson 《Earth and Planetary Science Letters》1988,91(1-2)

In a series of experiments at 0.5–1.3 GPa and 1050–1200°C we have monitored the transport, via crack propagation, of CO₂ into well-annealed olivine and quartz aggregates. The objectives were to determine (1) the extent and rate of fluid penetration; (2) the effect of varying both P-T conditions and microstructure; and (3) the fluid penetration pathways. Experiments on CO₂ penetration into dunite annealed in the absence of MgO indicate rapid and pervasive fluid transport on a grain-dimension scale, but a limited penetration distance ( 1 mm). Additional experiments on dunite annealed in the presence of MgO (either dispersed or present at both ends), however, resulted in CO₂ penetration that was both pervasive on the scale of individual grains and almost always completely through the 5 mm long samples. The abundance of fine (10 μm) grains in the MgO-free dunite, in contrast to the much larger grain sizes of the samples annealed with MgO present, suggests the difference in fluid penetration behavior may arise because the strength variation in dunite scales with the grain size. Effects arising from changes in olivine point defect chemistry, however, are an additional possibility. The response of synthetic quartzite to CO₂ overpressure is distinct from that of dunite: Quartzite experiences rapid and complete penetration of CO₂, via a macroscopically visible system of transgranular fractures, over the range of P-T conditions investigated.The small amount of porosity ( 2–3%) present in most rock samples fabricated for this study, lacks three-dimensional connectivity, thus precluding any enhanced fluid penetration via porous flow. Pores could possibly enhance fluid penetration as the result of a small reduction in resistance to fracture, but the probable abundance of strength-controlling flaws in natural rocks is likely to produce similar behavior.The results of our experiments on olivine and olivine + MgO suggest that the transport of pressurized CO₂ in very olivine-rich mantle environments will be pervasive on the scale of individual grains and its extent may be dependent on rock microstructure and/or crystal chemical effects. Such pervasive fluid transport, perhaps associated with magma decarbonation, may have interesting implications for both magma transport and local LREE enrichment of adjacent mantle wall-rock. The ease with which quartzite is penetrated by CO₂ at the conditions of our experiments underscores the possible role of decarbonation reactions in crustal permeability-enhancement processes.  相似文献   

Comparison of amplitude decay rates in reflection,refraction, and local earthquake records     

Bruce S. Gibson 《Pure and Applied Geophysics》1988,128(1-2):309-331

Three types of seismic data recorded near Coalinga, California were analyzed to study the behavior of scattered waves: 1) aftershocks of the May 2, 1983 earthquake, recorded on verticalcomponent seismometers deployed by the USGS; 2) regional refraction profiles using large explosive sources recorded on essentially the same arrays above; 3) three common-midpoint (CMP) reflection surveys recorded with vibrator sources over the same area. Records from each data set were bandpassed filtered into 5 Hz wide passbands (over the range of 1–25 Hz), corrected for geometric spreading, and fit with an exponential model of amplitude decay. Decay rates were expressed in terms of inverse codaQ (Q _c ^–1 ).Q _c ^–1 values for earthquake and refraction data are generally comparable and show a slight decrease with increasing frequency. Decay rates for different source types recorded on proximate receivers show similar results, with one notable exception. One set of aftershocks shows an increase ofQ _c ^–1 with frequency.Where the amplitude decay rates of surface and buried sources are similar, the coda decay results are consistent with other studies suggesting the importance of upper crustal scattering in the formation of coda. Differences in the variation ofQ _c ^–1 with frequency can be correlated with differences in geologic structure near the source region, as revealed by CMP-stacked reflection data. A more detailed assessment of effects such as the depth dependence of scattered contributions to the coda and the role of intrinsic attenuation requires precise control of source-receiver field geometry and the study of synthetic seismic data calculated for velocity models developed from CMP reflection data.  相似文献   

Generation of Hydrogen Gas as a Result of Drilling Within the Saturated Zone   总被引：1，自引：0，他引：1  

Bruce N. Bjornstad  James P. McKinley  Todd O. Stevens  Shirley A. Rawson  James K. Fredrickson  Philip E. Long 《Ground Water Monitoring & Remediation》1994,14(4):140-147

Hydrogen gas was discovered within the steel casing above standing water in a percussion-drilled borehole on the Hanlord Site in south-central Washington state. In situ measurements of the borehole fluids indicated anoxic, low-Eh (<-400 mV) conditions. Ground water sampled from adjacent wells in the same formation indicated that the ground water was oxygenated. H₂ was generated during percussion drilling, due to the decomposition of borehole waters as a result of aqueous reactions with drilled sediment and steel from the drilling tools or casing. The generation of H₂ within percussion-drilled boreholes that extend below the water table may be more common than previously realized. The ambient concentration of H₂ produced during drilling was limited by microbial activity within the casing-resident fluids. H₂ was generated abiotically in the laboratory, whereby sterilized borehole slurry samples produced 100 times more H₂ than unsterilizcd samples. It appears that H₂ is metabolized by microorganisms and concentrations might be significantly greater if not for microbial metabolism.  相似文献   

Genetic structure of bay anchovy (Anchoa mitchilli) populations in Chesapeake Bay     

Raymond P. Morgan  Bruce M. Baker  James H. Howard 《Estuaries and Coasts》1995,18(3):482-493

To determine the genetic structure of the bay anchovy (Anchoa mitchilli) within Chesapeake Bay, 16 isozyme systems encoding 21 loci for 20 population were examined using horizontal starch gel electrophoresis. Contingency Chisquare analysis revealed significant allelic frequency differences at nine loci (AAT-1, AAT-2, ALD-1, CPK-2, GAP-1, GLY-1, LDH-1, MDH-1, and MDH-2). Two loci, ALD-1 and MDH-1, were responsible for nine of 14 tests not conforming to Hardy-Weinberg expectations, with some of these deviations attributed to possible scoring and/or sampling error. Estimates for mean average heterozygosity were relatively high, ranging from 0.40 to 0.096, with 33–57% of the loci polymorphic. A low F_st value (0.041) along with high genetic identity estimates (I=0.997) indicated little substructuring of bay anchovy populations within Chesapeake Bay.  相似文献   

INSTITUTIONAL OBSTACLES TO SUSTAINABLE DEVELOPMENT IN BALI, INDONESIA     

Bruce Mitchell 《Singapore journal of tropical geography》1995,15(2):145-156

Developing and implementing sustainable development strategies involve overcoming many obstacles. The experience in Bali, Indonesia, illustrates some key institutional challenges which most countries must handle to achieve sustainable development, such as realising cross-sectoral integration, combining top-down and bottom-up planning, and creating credibility for a new policy initiative. Indonesia in general and Bali in particular has, in theory, considerable capability to implement sustainable development. However, as in most countries, effective practice does not always follow from theoretical potential. Strengths and weaknesses related to institutional challenges are identified and assessed, and their general implications are considered. Some key implications are the need to develop sustainable development strategies which reflect the conditions and needs specific to the targetted region, and to address different national and regional perspectives.  相似文献   

Energy market failure in road transport: Is there scope for ‘no regrets’ greenhouse gas reduction?     

Barry Naughten  Bruce Bowen  Tony Beck 《Climatic change》1993,25(3-4):271-288

The Australian Government policy on reduction of greenhouse gas emissions announced in 1990 includes exploring the scope for immediate, low cost reductions. Such measures can be taken as including ‘no regrets’ policies: those that, in addition to mitigating potential climate change, confer economic gains (including other environmental benefits) which exceed their costs. Some possible ‘no regrets’ opportunities and policies are identified relevant to energy use by the road transport sector over the period to 2020. The MARKALMENSA multi-period linear programming model of the Australian energy sector is used to investigate the cost-effectiveness of these policies.  相似文献   

World Data Center-A for Paleoclimatology at the NOAA Paleoclimatology Program,Boulder, CO     

Robert S. Webb  Jonathan T. Overpeck  David M. Anderson  Bruce A. Bauer  Mildred K. England  Wendy S. Gross  E. Ann Meyers  Michael M. Worobec 《Journal of Paleolimnology》1993,9(1):69-75

Conclusion The World Data Center-A for Paleoclimatology, located in the NOAA/NGDC Paleoclimatology Program, is committed to providing the scientific community with easy access to all paleoenvironmental data. Efforts to make archived data readily available include international coordination of data acquisition, management, and distribution, sponsoring workshops and data cooperatives to facilitate the compilation of important data sets, development of a browse and visualization software package (PaleoVu), and dispersal of archived data on magnetic media or over ANONYMOUS FTP/INTERNET. The program publishes a semi-annual newsletter that highlights latest developments and accomplishments in the area of paleoenvironmental data for global change research. Contributions to the newsletter are welcome from researchers describing their efforts to coordinate the free flow of paleoclimate data throughout the international scientific community.For information on the program or to be added to the mailing list contact Mrs Mildred England (phone: 303-497-6227; Fax: 303 497-6513; e-mail: MKE@mail.ngdc.noaa.gov), NOAA National Geophysical Data Center, Paleoclimatology Program/World Data Center-A for Paleoclimatology, 325 Broadway, E/GC Boulder, CO 80303 USA  相似文献   

Petrology and geochemistry of komatiites and tholeiites from Gorgona Island,Colombia   总被引：2，自引：0，他引：2  

Aitken  Bruce G.  Echeverría  Lina M. 《Contributions to Mineralogy and Petrology》1984,86(1):94-105

Komatiitic rocks from Gorgona Island, Colombia, in contrast to their Archaean counterparts, occur as rather structureless flows. In addition, textural and mineralogical features indicate that the Gorgona komatiites may have crystallized from superheated liquids. Komatiitic rocks have MgO contents which range from 24 to 11 wt.% and plot on well-defined olivine (Fo₉₀) control lines. Calculations show that potential evolved liquids (MgO<11 wt%) will be SiO₂-poor. Komatiites, in this case, cannot be regarded as parental to the associated tholeiitic basalt sequence.On the basis of REE concentrations and Sr, Nd isotopic compositions, the associated basalts are found to be of two types. One type (K-tholeiite) is characterized by noticeably fractionated REE patterns and relatively primitive isotopic compositions similar to those of the komatiites. K-tholeiites, together with komatiites, are regarded as comprising a distinctive komatiitic suite. REE patterns within this suite show progressive depletion in the LREE from K-tholeiites to komatiites, and represent increasingly higher degrees of melting of the same mantle source region. The other type (T-tholeiite), representative of the bulk of the exposed basalt sequence, has flat REE patterns and relatively evolved isotopic compositions. This tholeiitic suite is clearly genetically unrelated to the komatiitic suite.  相似文献   

The behavior of apatite during crustal anatexis: Equilibrium and kinetic considerations   总被引：5，自引：0，他引：5  

T.Mark Harrison  E.Bruce Watson 《Geochimica et cosmochimica acta》1984,48(7):1467-1477

The solubility and dissolution kinetics of apatite in felsic melts at 850°–1500°C have been examined experimentally by allowing apatite crystals to partially dissolve into apatite-undersaturated melts containing 0–10 wt% water. Analysis of P and Ca gradients in the crystal/melt interfacial region enables determination of both the diffusivities and the saturation levels of these components in the melt. Phosphorus diffusion was identified as the rate-limiting factor in apatite dissolution. Results of four experiments at 8 kbar run in the virtual absence of water yield an activation energy (E) for P diffusion of 143.6 ± 2.8 kcal-mol^?1 and frequency factor (D₀) of 2.23^+2.88_?1.26 × 10⁹cm²-sec^?1. The addition of water causes dramatic and systematic reduction of both E and D₀ such that at 6 wt% H₂O the values are ~25 kcal-mol^?1 and 10^?5 cm²-sec^?1, respectively. At 1300°C, the diffusivity of P increases by a factor of 50 over the first 2% of water added to the melt, but rises by a factor of only two between 2 and 6%, perhaps reflecting the effect of a concentration-dependent mechanism of H₂O solution. Calcium diffusion gradients do not conform well to simple diffusion theory because the release of calcium at the dissolving crystal surface is linked to the transport rate of phosphorus in the melt, which is typically two orders of magnitude slower than Ca. Calcium chemical diffusion rates calculated from the observed gradients are about 50 times slower than calcium tracer diffusion.Apatite solubilities obtained from these experiments, together with previous results, can be described as a function of absolute temperature (T) and melt composition by the expression: In D^apatite/melt_P = [(8400 + ((SiO₂ ? 0.5)2.64 × 10⁴))/T] ? [3.1 + (12.4(SiO₂ ? 0.5))] where SiO₂ is the weight fraction of silica in the melt. This model appears to be valid between 45% and 75% SiO₂, 0 and 10% water, and for the range of pressures expected in the crust.The diffusivity information extracted from the experiments can be directly applied to several problems of geochemical interest, including I) dissolution times for apatite during crustal anatexis, and 2) pileup of P, and consequent local saturation in apatite, at the surfaces of growing major-mineral phases.  相似文献